Por favor, use este identificador para citar o enlazar este ítem: http://www.dspace.uce.edu.ec/handle/25000/14843
Título : Lost chapter of Physical Chemistry means convergence between Fisher–Kolmogorov equation and tunnel effect
Otros títulos : Lost chapter of Physical Chemistry means convergence between Fisher–Kolmogorov equation and tunnel effect.
Autor : Jiménez, Edward
Mosquera, Héctor
Cortez, Marco
Jiménez, Esteban
Ayala, Carlos
López, Gustavo
Ullrich, Stahl
Palabras clave : ECUACIÓN DE FISHER-KOLMOGOROV
EFECTO TÚNEL CUÁNTICO
TEMPERATURAS ULTRABAJAS
CATÁLISIS
Fecha de publicación : 2016
Editorial : New York: Cornell University Library
Citación : Jiménez, Edward y otros (2016). Lost chapter of Physical Chemistry means convergence between Fisher–Kolmogorov equation and tunnel effect. Physics.Chem-PH: 1-43
Resumen : In this work we show that the dynamics of chemical reactions of order zero, one and two have a representation through logistics probability. This probability is robust, stable and complies systemically with the differential equation of Fisher-Kolmogorov (F-K). It is robust, because in theorem 1 and theorem 3 differential equations of diffusion and heat transfer are obtained, where the temperature plays a key role. Also, the Eikonal equation of wave mechanics allows us to construct the heat equation. In Lemma 2, Fick´s diffusion equation is demonstrated. It is stable, because probability convergence when t→∞, gives us new ways to analyze the kinetics of a reaction integrally, in Corollary 5. Finally, the theoretically and experimentally obtained algorithms and results support the convergence in probability of the quantum tunnel effect and chemical reactions for: hydrogen production at ultra-low temperature and catalytic cracking of asphalt at high temperature.
URI : http://www.dspace.uce.edu.ec/handle/25000/14843
Aparece en las colecciones: Artículos Indexados - IM

Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
Lost chapter of Physical Chemistry means convergence between Fisher–Kolmogorov equation and tunnel effect..pdfARTÍCULO A TEXTO COMPLETO1.3 MBAdobe PDFVisualizar/Abrir


Los ítems de DSpace están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.